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The Improved Oil Removal Using Polysulfone Membranes Containing Al2O3 Nanoparticles

Year 2017, Özel Sayı 2, 63 - 68, 23.11.2017

S Saki Niğmet Uzal N Ateş

Abstract



Oil-intensive industries produce environmentally problematic wastewaters
and their treatment is more difficult because of their high stability in
aqueous solutions. Although conventional separation methods are used for the
removal of oily compounds, these processes cannot satisfy environmental
regulations. Therefore membrane separation processes such as microfiltration
(MF) and ultrafiltration (UF) have gained attention to separate micron sized
oily compounds. Many researchers have studied to increase the oil removal
performance of membrane filtration by incorporating nanoparticles to the
membrane matrix. In this study, the flat-sheet PSF/PEI/Al2O3
nanocomposite membranes were prepared by a phase inversion method for oil
removal. The oil removal performances of the membranes were evaluated with
1,800 mg/L synthetic wastewater. 20 nm Al2O3 nanoparticles
was added to the membrane matrix with three different weight percentages of 0.2
wt%, 1 wt% and 5 wt%. The effect of Al2O3 nanoparticles on
the structural properties and filtration performance of the membranes were
investigated. Prepared membranes were characterized in terms of SEM, contact
angle, water flux, porosity, ATR-FTIR, porosity and tensile strength. The
highest oil removal efficiency was obtained by 15 wt% PSF, 1 wt% PEI and 0.2% wt
Al2O3 nanoparticles blended nanocomposite membrane with
an oil rejection of 99 %.

Keywords

oil removal polysulfone membranes Al2O3 nanoparticles

References

  • Chakrabarty, B., Ghoshal, A. and Purkait, M. (2010) Cross-flow ultrafiltration of stable oil-in-water emulsion using polysulfone membranes. Chemical Engineering Journal 165(2), 447-456.
  • Costa, T.M., Gallas, M.R., Benvenutti, E.V. and da Jornada, J.A. (1999) Study of nanocrystalline γ-Al2O3 produced by high-pressure compaction. The Journal of Physical Chemistry B 103(21), 4278-4284.
  • Fenu, A., Guglielmi, G., Jimenez, J., Spèrandio, M., Saroj, D., Lesjean, B., Brepols, C., Thoeye, C. and Nopens, I. (2010) Activated sludge model (ASM) based modelling of membrane bioreactor (MBR) processes: A critical review with special regard to MBR specificities. Water Research 44(15), 4272-4294.
  • Ghandashtani, M.B., Zokaee Ashtiani, F., Karimi, M. and Fouladitajar, A. (2015) A novel approach to fabricate high performance nano-SiO2 embedded PES membranes for microfiltration of oil-in-water emulsion. Applied Surface Science 349, 393-402.
  • Gohari, R.J., Korminouri, F., Lau, W., Ismail, A., Matsuura, T., Chowdhury, M., Halakoo, E. and Gohari, M.J. (2015) A novel super-hydrophilic PSf/HAO nanocomposite ultrafiltration membrane for efficient separation of oil/water emulsion. Separation and Purification Technology 150, 13-20.
  • Hong, J. and He, Y. (2014) Polyvinylidene fluoride ultrafiltration membrane blended with nano-ZnO particle for photo-catalysis self-cleaning. Desalination 332(1), 67-75.
  • Jamal, S., Chang, S. and Zhou, H. (2014) Filtration behaviour and fouling mechanisms of polysaccharides. Membranes 4(3), 319-332.
  • Jamshidi Gohari, R., Halakoo, E., Lau, W.J., Kassim, M.A., Matsuura, T. and Ismail, A.F. (2014) Novel polyethersulfone (PES)/hydrous manganese dioxide (HMO) mixed matrix membranes with improved anti-fouling properties for oily wastewater treatment process. RSC Advances 4(34), 17587-17596.
  • Kajitvichyanukul, P., Hung, Y.-T. and Wang, L.K. (2011) Membrane and Desalination Technologies. Wang, L.K., Chen, J.P., Hung, Y.-T. and Shammas, N.K. (eds), pp. 639-668, Humana Press, Totowa, NJ.
  • Kumar, R., Isloor, A.M., Ismail, A.F., Rashid, S.A. and Ahmed, A.A. (2013) Permeation, antifouling and desalination performance of TiO2 nanotube incorporated PSf/CS blend membranes. Desalination 316, 76-84.
  • Li, X.-y. and Chu, H.P. (2003) Membrane bioreactor for the drinking water treatment of polluted surface water supplies. Water Research 37(19), 4781-4791.
  • Lohokare, H., Bhole, Y., Taralkar, S. and Kharul, U. (2011) Poly(acrylonitrile) based ultrafiltration membranes: Optimization of preparation parameters. Desalination 282, 46-53.
  • Lotfiyan, H., Zokaee Ashtiani, F., Fouladitajar, A. and Armand, S.B. (2014) Computational fluid dynamics modeling and experimental studies of oil-in-water emulsion microfiltration in a flat sheet membrane using Eulerian approach. Journal of Membrane Science 472, 1-9.
  • Maximous, N., Nakhla, G., Wan, W. and Wong, K. (2009) Preparation, characterization and performance of Al2O3/PES membrane for wastewater filtration. Journal of Membrane Science 341(1–2), 67-75.
  • Mueller, J., Cen, Y. and Davis, R.H. (1997) Crossflow microfiltration of oily water. Journal of Membrane Science 129(2), 221-235.
  • Srijaroonrat, P., Julien, E. and Aurelle, Y. (1999) Unstable secondary oil/water emulsion treatment using ultrafiltration: fouling control by backflushing. Journal of Membrane Science 159(1), 11-20.
  • Um, M.-J., Yoon, S.-H., Lee, C.-H., Chung, K.-Y. and Kim, J.-J. (2001) Flux enhancement with gas injection in crossflow ultrafiltration of oily wastewater. Water Research 35(17), 4095-4101.
  • van Reis, R. and Zydney, A. (2007) Bioprocess membrane technology. Journal of Membrane Science 297(1–2), 16-50.
  • Way, H., Forum, B. and DT11, D. (1992) The treatment of oily water by coalescing. Filtration & Separation 29(4), 295300-295298.
  • Yi, X.S., Shi, W.X., S.L.Yu, Ma, C., Sun, N., Wang, S., Jin, L.M. and Sun, L.P. (2011) Optimization of complex conditions by response surface methodology for APAM–oil/water emulsion removal from aqua solutions using nano-sized TiO2/Al2O3 PVDF ultrafiltration membrane. Journal of Hazardous Materials 193, 37-44.
  • Yunos, M.Z., Harun, Z., Basri, H. and Ismail, A.F. (2014) Studies on fouling by natural organic matter (NOM) on polysulfone membranes: Effect of polyethylene glycol (PEG). Desalination 333(1), 36-44.
  • Zhang, Y., Cui, P., Du, T., Shan, L. and Wang, Y. (2009) Development of a sulfated Y-doped nonstoichiometric zirconia/polysulfone composite membrane for treatment of wastewater containing oil. Separation and Purification Technology 70(2), 153-159.

Year 2017, Özel Sayı 2, 63 - 68, 23.11.2017

S Saki Niğmet Uzal N Ateş

Abstract

References

  • Chakrabarty, B., Ghoshal, A. and Purkait, M. (2010) Cross-flow ultrafiltration of stable oil-in-water emulsion using polysulfone membranes. Chemical Engineering Journal 165(2), 447-456.
  • Costa, T.M., Gallas, M.R., Benvenutti, E.V. and da Jornada, J.A. (1999) Study of nanocrystalline γ-Al2O3 produced by high-pressure compaction. The Journal of Physical Chemistry B 103(21), 4278-4284.
  • Fenu, A., Guglielmi, G., Jimenez, J., Spèrandio, M., Saroj, D., Lesjean, B., Brepols, C., Thoeye, C. and Nopens, I. (2010) Activated sludge model (ASM) based modelling of membrane bioreactor (MBR) processes: A critical review with special regard to MBR specificities. Water Research 44(15), 4272-4294.
  • Ghandashtani, M.B., Zokaee Ashtiani, F., Karimi, M. and Fouladitajar, A. (2015) A novel approach to fabricate high performance nano-SiO2 embedded PES membranes for microfiltration of oil-in-water emulsion. Applied Surface Science 349, 393-402.
  • Gohari, R.J., Korminouri, F., Lau, W., Ismail, A., Matsuura, T., Chowdhury, M., Halakoo, E. and Gohari, M.J. (2015) A novel super-hydrophilic PSf/HAO nanocomposite ultrafiltration membrane for efficient separation of oil/water emulsion. Separation and Purification Technology 150, 13-20.
  • Hong, J. and He, Y. (2014) Polyvinylidene fluoride ultrafiltration membrane blended with nano-ZnO particle for photo-catalysis self-cleaning. Desalination 332(1), 67-75.
  • Jamal, S., Chang, S. and Zhou, H. (2014) Filtration behaviour and fouling mechanisms of polysaccharides. Membranes 4(3), 319-332.
  • Jamshidi Gohari, R., Halakoo, E., Lau, W.J., Kassim, M.A., Matsuura, T. and Ismail, A.F. (2014) Novel polyethersulfone (PES)/hydrous manganese dioxide (HMO) mixed matrix membranes with improved anti-fouling properties for oily wastewater treatment process. RSC Advances 4(34), 17587-17596.
  • Kajitvichyanukul, P., Hung, Y.-T. and Wang, L.K. (2011) Membrane and Desalination Technologies. Wang, L.K., Chen, J.P., Hung, Y.-T. and Shammas, N.K. (eds), pp. 639-668, Humana Press, Totowa, NJ.
  • Kumar, R., Isloor, A.M., Ismail, A.F., Rashid, S.A. and Ahmed, A.A. (2013) Permeation, antifouling and desalination performance of TiO2 nanotube incorporated PSf/CS blend membranes. Desalination 316, 76-84.
  • Li, X.-y. and Chu, H.P. (2003) Membrane bioreactor for the drinking water treatment of polluted surface water supplies. Water Research 37(19), 4781-4791.
  • Lohokare, H., Bhole, Y., Taralkar, S. and Kharul, U. (2011) Poly(acrylonitrile) based ultrafiltration membranes: Optimization of preparation parameters. Desalination 282, 46-53.
  • Lotfiyan, H., Zokaee Ashtiani, F., Fouladitajar, A. and Armand, S.B. (2014) Computational fluid dynamics modeling and experimental studies of oil-in-water emulsion microfiltration in a flat sheet membrane using Eulerian approach. Journal of Membrane Science 472, 1-9.
  • Maximous, N., Nakhla, G., Wan, W. and Wong, K. (2009) Preparation, characterization and performance of Al2O3/PES membrane for wastewater filtration. Journal of Membrane Science 341(1–2), 67-75.
  • Mueller, J., Cen, Y. and Davis, R.H. (1997) Crossflow microfiltration of oily water. Journal of Membrane Science 129(2), 221-235.
  • Srijaroonrat, P., Julien, E. and Aurelle, Y. (1999) Unstable secondary oil/water emulsion treatment using ultrafiltration: fouling control by backflushing. Journal of Membrane Science 159(1), 11-20.
  • Um, M.-J., Yoon, S.-H., Lee, C.-H., Chung, K.-Y. and Kim, J.-J. (2001) Flux enhancement with gas injection in crossflow ultrafiltration of oily wastewater. Water Research 35(17), 4095-4101.
  • van Reis, R. and Zydney, A. (2007) Bioprocess membrane technology. Journal of Membrane Science 297(1–2), 16-50.
  • Way, H., Forum, B. and DT11, D. (1992) The treatment of oily water by coalescing. Filtration & Separation 29(4), 295300-295298.
  • Yi, X.S., Shi, W.X., S.L.Yu, Ma, C., Sun, N., Wang, S., Jin, L.M. and Sun, L.P. (2011) Optimization of complex conditions by response surface methodology for APAM–oil/water emulsion removal from aqua solutions using nano-sized TiO2/Al2O3 PVDF ultrafiltration membrane. Journal of Hazardous Materials 193, 37-44.
  • Yunos, M.Z., Harun, Z., Basri, H. and Ismail, A.F. (2014) Studies on fouling by natural organic matter (NOM) on polysulfone membranes: Effect of polyethylene glycol (PEG). Desalination 333(1), 36-44.
  • Zhang, Y., Cui, P., Du, T., Shan, L. and Wang, Y. (2009) Development of a sulfated Y-doped nonstoichiometric zirconia/polysulfone composite membrane for treatment of wastewater containing oil. Separation and Purification Technology 70(2), 153-159.
There are 22 citations in total.

Details

Subjects Engineering
Journal Section Full-length articles
Authors

S Saki This is me

Niğmet Uzal

N Ateş This is me

Publication Date November 23, 2017
Submission Date December 12, 2017
Acceptance Date December 21, 2017
Published in Issue Year 2017 Özel Sayı 2

Cite

APA Saki, S., Uzal, N., & Ateş, N. (2017). The Improved Oil Removal Using Polysulfone Membranes Containing Al2O3 Nanoparticles. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 1(Sp. is. 2), 63-68.

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This piece of scholarly information is licensed under Creative Commons Atıf-GayriTicari-AynıLisanslaPaylaş 4.0 Uluslararası Lisansı.

J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)