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An Evaluation of Vanadium Enrichment in the Eastern Shelf Sediments of the Turkish Black Sea

Year 2017, Volume: 4 Issue: 2, 128 - 138, 15.05.2017
https://doi.org/10.30897/ijegeo.312661

Abstract

This paper presents an
evaluation of the spatial distribution of vanadium level, its enrichment and
possible sources in the bottom sediment along the shelf of the Turkish Black
Sea. In April 2006, vanadium concentrations were measured along the measurement
profiles (20, 50 and 100 m) using ICP-MS. The vanadium levels ranged from 40 to
315 µg g-1, usually within the range of typical and background
values (Cf<1), except the one
offshore the Yeşilırmak River (315.2 µg g-1), revealing significant
riverine inputs and geographical conditions (Cf>3). The concentrations decrease gradually with water depth,
implying the dominance of anthropogenic sources such as industrial wastes,
agricultural effluents, sewage discharge, and port activities. The vanadium
levels had not significant correlations with the physicochemical parameters
(sediment texture, water content, TOC) and TPH level in the sediment. At the
eastern basin, a serious vanadium enrichment (Cf>6-9) was observed in
October 2010, implying some important regional and seasonal contributions;
which may be natural or anthropogenic. Biogeochemical processes,
eutrophication, wave-based erosion, abnormal current circulations, bottom
morphology and influence of other substances in the environment may be other
regulating factors to this enrichment. Continuous monitoring and further
studies are required for a detailed description of vanadium mobility and for
assessment of the main controlling processes associated with vanadium
enrichment in the eastern Black Sea basin.

References

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  • Algan O, Gazioğlu C, Çağatay N, Yücel ZY., Gönençgil B. (1999). Sediment and water influxes into the Black Sea by Anatolian rivers. Zeitschrift für Geomorphologie 43,61–79.
  • Algan O., Gazioğlu C., Yücel Z., Çağatay N., Gönençgil B. (2000). Sediment and Freshwater Discharges of the Anatolian River into the Black Sea, IOC-BSRC Workshop «Black Sea Fluxes», Workshop Report No. 145. Paris: UNESCO, 38–50.
  • Algan, O., Gökaşan, E., Gazioğlu, C., Yücel, Z Alpar, B., Güneysu, C., Kırcı, E., Delta and Submarine canyon, southern Black Sea. Continental Shelf Research, 22(10), 1511–1527.
  • Atlas, L. and Büyükgüngör, H. (2007). Heavy metal pollution in the Black Sea shore and offshore of Turkey. Environmental Geology, 52, 469–476. Bat, L. and Özkan, E.Y. (2015). Chapter 13. Heavy metal levels in sediment of the Turkish Black Sea coast. In: Bikarska I, Raykov V, Nikolov N. (Eds.) Progressive Engineering Practices in Marine Resource Management. IGI Global book series Advances in Environmental Engineering and Green Technologies (AEEGT) (ISSN: 2326-9162; eISSN: 2326-9170) USA, pp. 399-419.
  • Bat, L., Özkan E.Y. and Öztekin, H.C. (2015). The contamination status of trace metals in Sinop coast of the Black Sea, Turkey. Caspian Journal of Environmental Sciences, 13 (1), 1-10.
  • El-Moselhy, Kh. M. (2006). Distribution of vanadium in bottom sediments from the marine coastal area of the Egyptian Seas. Egyptian Journal of Aquatic Research, 32(1), 12-21.
  • Håkanson, L. (1980). An ecological risk index for aquatic pollution control: A sedimentological approach. Water Research, 14, 975–1001.
  • Hay, B. J. (1994). Sediment and water discharge rates of Turkish Black Sea rivers before and after hydropower dam construction. Environmental Geology, 23, 276-283.
  • Inglett, P.W., Inglett, K.S. and Reddy, K.R. (2008). Biogeochemical processes and implications for nutrient cycling. In: Brown, M.T., Reiss, K.C., Cohen, M.J., Evans, J.M., Inglett, P.W., Inglett, K.S., Reddy, K.R., Frazer, T.K., Jacoby, C.A., Phlips, E.J., Knight, R,L., Notestein, S.K., Hamann, R.G., McKee, K.A. (Eds.), Summary and Synthesis of the Available Literature on the Effects of Nutrients on Spring Organisms and Systems. University of Florida Water Institute, 570 Weil Hall, Gainesville, FL 32611-6601.
  • Loring, D.H. and Rantala, R.T.T. (1992). Manual for the geochemical analyses of marine sediments and suspended particulate matter. Earth-Science Reviews, 32(4), 235– 283.
  • McLennan, S.M. and Murray, R.W. (1999). Geochemistry of sediments. In: Marshall, C.P., Fairbridge, R.W. (Eds.), Encyclopedia of Geochemistry. Kluwer Academic Publishers, Dordrecht, Germany, 282-292.
  • Metwally, M.E.S., Al-Muzaini, S., Jacob, P.G., Bahloul, M., Urushigawa, Y., Sato, S. and Matsmura, A. (1997). Petroleum hydrocarbons and related heavy metals in the near-shore marine sediments of Kuwait. Environment International, 3(1), 115–121.
  • Moore, J.W. (1991). Inorganic contaminants of surface water: research and monitoring priorities. Springer-Verlag, New York Inc. 334.
  • Murray, J.W., Top, Z. and Özsoy, E. (1991). Hydrographic properties and ventilation of the Black Sea. Deep-Sea Research, 38(Suppl.2A), S663–690.
  • Ramondetta, P.J. and Harris, W.H. (1976). Heavy metal distribution in Jamaica Bay sediments. Environmental Geology, 2, 145- 149.
  • Readman, J.W., Fillmann, G., Tolosa, I., Bartocci, J., Villeneuve, J.-P., Catinni, C. and Mee, L.D. (2002). Petroleum and PAH contamination of the Black Sea. Marine Pollution Bulletin, 44, 48–62.
  • Rehder, D. (2008). Bioinorganic Vanadium Chemistry (1st ed.). Hamburg, Germany: John Wiley and Sons, Ltd. 5, 9–10.
  • Romankevich, E.A. (1984). Geochemistry of organic matter in the ocean. Berlin, Heidelberg, New York: Springer and Verlag.
  • Ross, D.A. and Degens, E.T. (1974). Recent sediments of the Black Sea. In: Degens, E.T., Ross, D.A. (Eds.), The Black Sea - Geology, Chemistry, and Biology, The American Association of Petroleum Geologists, Memoir 20, Tulsa, Oklahama, 183–189.
  • Sur, M., Sur, H.İ., Apak, R. and Erçağ, E. (2012). The pollution status of bottom surface sediments along the Turkish coast of the Black Sea. Turkish Journal of Fisheries and Aquatic Sciences, 12, 453-460.
  • Taylor, S.R. (1972). Abundance of chemical elements in the continental crust: a new table. Geochemica Cosmochim Acta, 28, 1273–1286.
  • Tomlison, M.J., Wang, J. and Caruso, J.A. (1994). Speciation of toxicologically important transition metals using ion chromatography with inductively coupled plasma mass spectrometric detection. Journal of Analytical Atmospheric Spectrometry, 9, 957-964.
  • Turekian, K. K. and Wedepohl, K.H. (1961). Distribution of the elements in some major units of the Earth’s crust. Bulletin Geological Society of America, 72, 175- 192.
  • Ünlü, S. and Alpar, B. (2009). Hydrocarbon contamination in sediment offshore Yeşilırmak River, Black Sea, Turkey, In: E. Özhan (Ed.), Proceedings of the Ninth International Conference on the Mediterranean Coastal Environment, MEDCOAST 09, 2, 689–699.
  • Ünlü, S., Alpar, B. and Aydın, Ş. (2009). Spectrofluorometric characterization of aromatic hydrocarbon contamination in the sediment from the Zonguldak Industrial Region, Black Sea, Turkey. Fresenius Environmental Bulletin, 18, 474–480.
  • Varmuza, K. and Filzmoser, P. (2008). Introduction to multivariate statistical analysis in chemometrics. CRC Press, Taylor and Francis Group, Boca Raton, FL.
  • Wann, C. and Jiang, S. (1997). Determination of vanadium species in water samples by liquid chromatography-inductively coupled plasma mass spectrometry. Analytica Chimical Acta, 357 211-218.
  • Zaitsev Yu, Mamaev VO. (1997). Biological Ünlü and Alpar., IJEGEO, 4(2) 128-138 (2017) diversity in the Black Sea: A study of change and decline, Black Sea Environmental Series, Vol. 3, United Nations Publishing, New York, 208 pages
Year 2017, Volume: 4 Issue: 2, 128 - 138, 15.05.2017
https://doi.org/10.30897/ijegeo.312661

Abstract

References

  • Abdel Ghani, S.A., Shobier, A.H. Shreadah, M.A. (2013). Assessment of arsenic and vanadium pollution in surface sediments of the Egyptian Mediterranean coast. International Journal of Environmental Technology and Management, 16(1/2), 82- 101.
  • Algan O, Gazioğlu C, Çağatay N, Yücel ZY., Gönençgil B. (1999). Sediment and water influxes into the Black Sea by Anatolian rivers. Zeitschrift für Geomorphologie 43,61–79.
  • Algan O., Gazioğlu C., Yücel Z., Çağatay N., Gönençgil B. (2000). Sediment and Freshwater Discharges of the Anatolian River into the Black Sea, IOC-BSRC Workshop «Black Sea Fluxes», Workshop Report No. 145. Paris: UNESCO, 38–50.
  • Algan, O., Gökaşan, E., Gazioğlu, C., Yücel, Z Alpar, B., Güneysu, C., Kırcı, E., Delta and Submarine canyon, southern Black Sea. Continental Shelf Research, 22(10), 1511–1527.
  • Atlas, L. and Büyükgüngör, H. (2007). Heavy metal pollution in the Black Sea shore and offshore of Turkey. Environmental Geology, 52, 469–476. Bat, L. and Özkan, E.Y. (2015). Chapter 13. Heavy metal levels in sediment of the Turkish Black Sea coast. In: Bikarska I, Raykov V, Nikolov N. (Eds.) Progressive Engineering Practices in Marine Resource Management. IGI Global book series Advances in Environmental Engineering and Green Technologies (AEEGT) (ISSN: 2326-9162; eISSN: 2326-9170) USA, pp. 399-419.
  • Bat, L., Özkan E.Y. and Öztekin, H.C. (2015). The contamination status of trace metals in Sinop coast of the Black Sea, Turkey. Caspian Journal of Environmental Sciences, 13 (1), 1-10.
  • El-Moselhy, Kh. M. (2006). Distribution of vanadium in bottom sediments from the marine coastal area of the Egyptian Seas. Egyptian Journal of Aquatic Research, 32(1), 12-21.
  • Håkanson, L. (1980). An ecological risk index for aquatic pollution control: A sedimentological approach. Water Research, 14, 975–1001.
  • Hay, B. J. (1994). Sediment and water discharge rates of Turkish Black Sea rivers before and after hydropower dam construction. Environmental Geology, 23, 276-283.
  • Inglett, P.W., Inglett, K.S. and Reddy, K.R. (2008). Biogeochemical processes and implications for nutrient cycling. In: Brown, M.T., Reiss, K.C., Cohen, M.J., Evans, J.M., Inglett, P.W., Inglett, K.S., Reddy, K.R., Frazer, T.K., Jacoby, C.A., Phlips, E.J., Knight, R,L., Notestein, S.K., Hamann, R.G., McKee, K.A. (Eds.), Summary and Synthesis of the Available Literature on the Effects of Nutrients on Spring Organisms and Systems. University of Florida Water Institute, 570 Weil Hall, Gainesville, FL 32611-6601.
  • Loring, D.H. and Rantala, R.T.T. (1992). Manual for the geochemical analyses of marine sediments and suspended particulate matter. Earth-Science Reviews, 32(4), 235– 283.
  • McLennan, S.M. and Murray, R.W. (1999). Geochemistry of sediments. In: Marshall, C.P., Fairbridge, R.W. (Eds.), Encyclopedia of Geochemistry. Kluwer Academic Publishers, Dordrecht, Germany, 282-292.
  • Metwally, M.E.S., Al-Muzaini, S., Jacob, P.G., Bahloul, M., Urushigawa, Y., Sato, S. and Matsmura, A. (1997). Petroleum hydrocarbons and related heavy metals in the near-shore marine sediments of Kuwait. Environment International, 3(1), 115–121.
  • Moore, J.W. (1991). Inorganic contaminants of surface water: research and monitoring priorities. Springer-Verlag, New York Inc. 334.
  • Murray, J.W., Top, Z. and Özsoy, E. (1991). Hydrographic properties and ventilation of the Black Sea. Deep-Sea Research, 38(Suppl.2A), S663–690.
  • Ramondetta, P.J. and Harris, W.H. (1976). Heavy metal distribution in Jamaica Bay sediments. Environmental Geology, 2, 145- 149.
  • Readman, J.W., Fillmann, G., Tolosa, I., Bartocci, J., Villeneuve, J.-P., Catinni, C. and Mee, L.D. (2002). Petroleum and PAH contamination of the Black Sea. Marine Pollution Bulletin, 44, 48–62.
  • Rehder, D. (2008). Bioinorganic Vanadium Chemistry (1st ed.). Hamburg, Germany: John Wiley and Sons, Ltd. 5, 9–10.
  • Romankevich, E.A. (1984). Geochemistry of organic matter in the ocean. Berlin, Heidelberg, New York: Springer and Verlag.
  • Ross, D.A. and Degens, E.T. (1974). Recent sediments of the Black Sea. In: Degens, E.T., Ross, D.A. (Eds.), The Black Sea - Geology, Chemistry, and Biology, The American Association of Petroleum Geologists, Memoir 20, Tulsa, Oklahama, 183–189.
  • Sur, M., Sur, H.İ., Apak, R. and Erçağ, E. (2012). The pollution status of bottom surface sediments along the Turkish coast of the Black Sea. Turkish Journal of Fisheries and Aquatic Sciences, 12, 453-460.
  • Taylor, S.R. (1972). Abundance of chemical elements in the continental crust: a new table. Geochemica Cosmochim Acta, 28, 1273–1286.
  • Tomlison, M.J., Wang, J. and Caruso, J.A. (1994). Speciation of toxicologically important transition metals using ion chromatography with inductively coupled plasma mass spectrometric detection. Journal of Analytical Atmospheric Spectrometry, 9, 957-964.
  • Turekian, K. K. and Wedepohl, K.H. (1961). Distribution of the elements in some major units of the Earth’s crust. Bulletin Geological Society of America, 72, 175- 192.
  • Ünlü, S. and Alpar, B. (2009). Hydrocarbon contamination in sediment offshore Yeşilırmak River, Black Sea, Turkey, In: E. Özhan (Ed.), Proceedings of the Ninth International Conference on the Mediterranean Coastal Environment, MEDCOAST 09, 2, 689–699.
  • Ünlü, S., Alpar, B. and Aydın, Ş. (2009). Spectrofluorometric characterization of aromatic hydrocarbon contamination in the sediment from the Zonguldak Industrial Region, Black Sea, Turkey. Fresenius Environmental Bulletin, 18, 474–480.
  • Varmuza, K. and Filzmoser, P. (2008). Introduction to multivariate statistical analysis in chemometrics. CRC Press, Taylor and Francis Group, Boca Raton, FL.
  • Wann, C. and Jiang, S. (1997). Determination of vanadium species in water samples by liquid chromatography-inductively coupled plasma mass spectrometry. Analytica Chimical Acta, 357 211-218.
  • Zaitsev Yu, Mamaev VO. (1997). Biological Ünlü and Alpar., IJEGEO, 4(2) 128-138 (2017) diversity in the Black Sea: A study of change and decline, Black Sea Environmental Series, Vol. 3, United Nations Publishing, New York, 208 pages
There are 29 citations in total.

Details

Subjects Engineering
Journal Section Research Articles
Authors

Selma Ünlü

Bedri Alpar

Publication Date May 15, 2017
Published in Issue Year 2017 Volume: 4 Issue: 2

Cite

APA Ünlü, S., & Alpar, B. (2017). An Evaluation of Vanadium Enrichment in the Eastern Shelf Sediments of the Turkish Black Sea. International Journal of Environment and Geoinformatics, 4(2), 128-138. https://doi.org/10.30897/ijegeo.312661