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The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method

Year 2013, Volume: 26 Issue: 3, 399 - 405, 02.10.2013

Halil Durak Yasar Genel Novruz Bashırov Genber Kerımov

Abstract

One of the significant boron compounds which are common substance in nature is ulexite. Ulexite is a sodium calcium boron hydrate, its chemical formula is Na2O2CaO5B2O316H2O , and it is thick with in Turkey. Lots of products are derived from boron minerals. One of them is boric acid. CaCl2 is used in many fields and this compound can be obtained by different processes. The aim of this study is producing CaCl2 by forming mathematical model for CaCl2 composing in the wake of the interaction of ulexite with hydrochloric acid solution. In the study, full factorial desing method has been used. Some of the parameters used in the process have been pegged, and the others have been regarded as variables. The pegged parameters are particle size, reaction time and stirring speed. Hydrochloric acid concentration, temperature and solid to liquid ratio have been regarded as variable factors in formation of mathematical model. The mathematical model of three-parameter full factorial desing mehtod and the mathematical model of the process have initially been assessed in dimensionless coordinate system, then the available values in the model have been computed by Student criteria, the validity of the formed model has been controlled by Fisher criteria. Henceforwards, the current model of the process has been formed in real coordinate system.

Keywords

ulexite calcium chloride full factorial desing mathematical model.

References

  • [1] Alexander, D.T.L., Schwandt, C., Fray, D.J., “Microstructural kinetics of phase transformations during electrochemical reduction of titanium dioxide in molten calcium chloride.” Acta Materialia 54(2006)2933-2944.
  • [2] Boncukcuoğlu, R., Kocakerim, M.M., Kocadağistan, E., Yılmaz, M.T., 2003. Recovery of boron of the sieve reject in the production of borax. Resources. Conserv. Recycl. 37, 147–157.
  • [3] Cestari, A.R., Vieria E.F.S., A.Mota, J., “The removal of an anionic red dye from aqueous solution using chitosan beads-The role of experimental factors on adsorption using a full factorial desing. Journal of Hazardous Materials, 160 (2008)337-343.
  • [4] Chen, F., Liu, H., Yang, H., Lai, S., Cheng, X., Xin, Y., Yang, B., Hou, H., Yao, Y., Zhang, S., Bu, G., Deng, Y., “ Quality attributes and cell wall properties of strawberries (Fragaria ananassa Duch.) under calcium chloride treatment.” Food Chemistry 126(2011)450-459.
  • [5] Kirk Othmer Encyclopedia of Chemical Technology, 4th Ed., John-Wiley and Sons Inc., N.Y., 1992
  • [6] Kum, C., Alkan, M. and Kocakerim, M.M., “Dissolution kinetics of calcined colemanite in ammonium chloride solution,” Hydrometalurgy, 36,359 (1994).
  • [7] Küçük, Ö., Kocakerim, M.M., 2005. Optimization of dissolution of ulexite in water saturated with sulphur dioxide. Chem. Eng. Process. 44 (9), 1005–1011.
  • [8] Köse, T.E., “Agricultural residue anion exchangerfor removal of dyestuff from wastewater using full factorial desing.” Deselination. 222(2008) 323330.
  • [9] Öztürk, N., Kavak, D., “Boron removal from aqueous solutions by batch adsorption onto cerium oxide using full factorial desing.” Desilanation .223(2008)106-112.
  • [10] Öztürk, N., Kavak, D., “Boron Removal from Aqueous Solutions by Adsorption on Waste Sepiolite Using Full Factorial Desing.” Adsorption 10: 245-257, 2004.
  • [11] Rodriguez, A.P., Leiro, R.F., Cerdan, M.E., Siso, M.I.G., Fernandez, M.B., “ Kluyveromyces lactis β-galactosidase crystallization using full-factorial experimental desing. Journal of Molecular Catalysis B: Enzymatic. 52-53 (2008) 178-182.
  • [12] Seki, Y., Seyhan, S., Yurdakoc,M., “Removal of boron from aqueous solution by adsorption on Al2O3 based materials using full factorial desing.” Journal of Hazardous Materials B138(2006)60- 66.
  • [13] Salafranca, J., Cacho, J., Nerin, C., “Supercritical Fluid Extraction (SFE) Optimization by Full Factorial Desing fort he Determination of Irganox 1076, Irgafos 168, and Chimassorb 81 in Virgin and Recycled Polyolefins.” J. High Resol. Chromatogr. 1999,22,(10)553-558.
  • [14] Trezona, R.I., Pickles, M.J., Hutchings, I.M., “A full factorial investigation of erosion durability of automotive clearcoats.” Tribology International 33(2000)559-571.

Year 2013, Volume: 26 Issue: 3, 399 - 405, 02.10.2013

Halil Durak Yasar Genel Novruz Bashırov Genber Kerımov

Abstract

References

  • [1] Alexander, D.T.L., Schwandt, C., Fray, D.J., “Microstructural kinetics of phase transformations during electrochemical reduction of titanium dioxide in molten calcium chloride.” Acta Materialia 54(2006)2933-2944.
  • [2] Boncukcuoğlu, R., Kocakerim, M.M., Kocadağistan, E., Yılmaz, M.T., 2003. Recovery of boron of the sieve reject in the production of borax. Resources. Conserv. Recycl. 37, 147–157.
  • [3] Cestari, A.R., Vieria E.F.S., A.Mota, J., “The removal of an anionic red dye from aqueous solution using chitosan beads-The role of experimental factors on adsorption using a full factorial desing. Journal of Hazardous Materials, 160 (2008)337-343.
  • [4] Chen, F., Liu, H., Yang, H., Lai, S., Cheng, X., Xin, Y., Yang, B., Hou, H., Yao, Y., Zhang, S., Bu, G., Deng, Y., “ Quality attributes and cell wall properties of strawberries (Fragaria ananassa Duch.) under calcium chloride treatment.” Food Chemistry 126(2011)450-459.
  • [5] Kirk Othmer Encyclopedia of Chemical Technology, 4th Ed., John-Wiley and Sons Inc., N.Y., 1992
  • [6] Kum, C., Alkan, M. and Kocakerim, M.M., “Dissolution kinetics of calcined colemanite in ammonium chloride solution,” Hydrometalurgy, 36,359 (1994).
  • [7] Küçük, Ö., Kocakerim, M.M., 2005. Optimization of dissolution of ulexite in water saturated with sulphur dioxide. Chem. Eng. Process. 44 (9), 1005–1011.
  • [8] Köse, T.E., “Agricultural residue anion exchangerfor removal of dyestuff from wastewater using full factorial desing.” Deselination. 222(2008) 323330.
  • [9] Öztürk, N., Kavak, D., “Boron removal from aqueous solutions by batch adsorption onto cerium oxide using full factorial desing.” Desilanation .223(2008)106-112.
  • [10] Öztürk, N., Kavak, D., “Boron Removal from Aqueous Solutions by Adsorption on Waste Sepiolite Using Full Factorial Desing.” Adsorption 10: 245-257, 2004.
  • [11] Rodriguez, A.P., Leiro, R.F., Cerdan, M.E., Siso, M.I.G., Fernandez, M.B., “ Kluyveromyces lactis β-galactosidase crystallization using full-factorial experimental desing. Journal of Molecular Catalysis B: Enzymatic. 52-53 (2008) 178-182.
  • [12] Seki, Y., Seyhan, S., Yurdakoc,M., “Removal of boron from aqueous solution by adsorption on Al2O3 based materials using full factorial desing.” Journal of Hazardous Materials B138(2006)60- 66.
  • [13] Salafranca, J., Cacho, J., Nerin, C., “Supercritical Fluid Extraction (SFE) Optimization by Full Factorial Desing fort he Determination of Irganox 1076, Irgafos 168, and Chimassorb 81 in Virgin and Recycled Polyolefins.” J. High Resol. Chromatogr. 1999,22,(10)553-558.
  • [14] Trezona, R.I., Pickles, M.J., Hutchings, I.M., “A full factorial investigation of erosion durability of automotive clearcoats.” Tribology International 33(2000)559-571.
There are 14 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Chemical Engineering
Authors

Halil Durak

Yasar Genel This is me

Novruz Bashırov This is me

Genber Kerımov This is me

Publication Date October 2, 2013
Published in Issue Year 2013 Volume: 26 Issue: 3

Cite

APA Durak, H., Genel, Y., Bashırov, N., Kerımov, G. (2013). The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method. Gazi University Journal of Science, 26(3), 399-405.
AMA Durak H, Genel Y, Bashırov N, Kerımov G. The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method. Gazi University Journal of Science. October 2013;26(3):399-405.
Chicago Durak, Halil, Yasar Genel, Novruz Bashırov, and Genber Kerımov. “The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method”. Gazi University Journal of Science 26, no. 3 (October 2013): 399-405.
EndNote Durak H, Genel Y, Bashırov N, Kerımov G (October 1, 2013) The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method. Gazi University Journal of Science 26 3 399–405.
IEEE H. Durak, Y. Genel, N. Bashırov, and G. Kerımov, “The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method”, Gazi University Journal of Science, vol. 26, no. 3, pp. 399–405, 2013.
ISNAD Durak, Halil et al. “The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method”. Gazi University Journal of Science 26/3 (October 2013), 399-405.
JAMA Durak H, Genel Y, Bashırov N, Kerımov G. The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method. Gazi University Journal of Science. 2013;26:399–405.
MLA Durak, Halil et al. “The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method”. Gazi University Journal of Science, vol. 26, no. 3, 2013, pp. 399-05.
Vancouver Durak H, Genel Y, Bashırov N, Kerımov G. The Formation of Mathematical Model for CaCl2 Derived from The Reaction of Ulexite and Hydrochloric Acid by Using Full Factorial Desing Method. Gazi University Journal of Science. 2013;26(3):399-405.