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Ceviz, Fındık ve Yerfıstığı Kabuklarını Kullanarak Sipermetrinin Çevreden Uzaklaştırılması

Year 2021, Volume: 10 Issue: 2, 362 - 369, 07.06.2021
https://doi.org/10.17798/bitlisfen.869932

Abstract

Dünya nüfusunun artması çevre kirliliğini de beraberinde getirmektedir. Çevrenin doğallığını bozabilecek herhangi bir müdahale havaya, toprağa ve suya etki ederek tüm ekosistemdeki canlılara ulaşabilmektedir. Bu yüzden çevre kirliliğini en aza çekebilmek çok güncel bir konudur. Bir taraftan artan nüfusun gıda ihtiyacını karşılayabilmek için kimyasallar yardımıyla üretilen ürünün verimi artarken diğer taraftan hedef dışındaki bölgelere de bu kimyasallar ulaşabilmektedir. Hedef dışı bölgelere ulaşan kimyasallar canlılar üzerine olumsuz etkiler oluşturabilmektedir. Bu çalışmada; Türkiye’de ve dünyada tarımcılıkta ürünlerin böcek istilasını engellemede yaygın olarak kullanılan cypermethrinin, ceviz, fındık ve yerfıstığı kabuklarını kullanarak, toprak veya suya geçişine engel olmak için laboratuvar ortamında yapılan deneylerle çevrenin korunabileceği konusunda çalışılmıştır. Ceviz, fındık ve yerfıstığı kabuklarının gözenekli yapısı bu kimyasalların toprağa ve suya geçmeden önce adsorbe olabileceğini gösterilmiştir. Böylece masrafsız bir yöntemle cypermethrini çevreye dağılmadan önce doğal malzemeler olan ceviz, fındık ve yerfıstığı kabuklarının gözenekli yapısına hapsederek hedef dışı bölgelere ulaşmasına engel olunabilecektir.

Supporting Institution

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Project Number

-

Thanks

Bu çalışmanın deneysel aşamasının gerçekleşmesinde desteklerini esirgemeyen Prof.Dr. Belgin Tunalı ve Dr.Öğ.Üyesi Neslihan Kaya Kınaytürk’e çok teşekkür ederim.

References

  • Altıkat A., Turan T., Ekmekyapar Torun F. 2009. Türkiye’de Pestisit Kullanımı ve Çevreye Olan Etkileri. Atatürk Üniversitesi Ziraat Faültesi Dergisi, 40 (2): 87-92.
  • Hernández A.F., Parrónb T., Tsatsakis A.M., Requena M., Alarcón R., López-Guarnido O. 2013. Toxic effects of pesticide mixtures at a molecular level: Their relevance to human health. Toxicology, 307: 136-145.
  • Alavanja M.C., Hoppin J.A., Kamel F. 2004. Health Effects of Chronic Pesticide Exposure: Cancer and Neurotoxicity. Annual Review of Public Health, 25: 155-197.
  • Huang J., Qiao F., Zhang L., Rozelle S. 2000. Farm Pesticide, Rice Production and Human Health. CCAP's Project Report, 1-54.
  • Konstantinou I.K., Hela D.G., Albanis T.A. 2006. The status of pesticide pollution in surface waters (rivers and lakes) of Greece. Part I. Review on occurrence and levels. Environmental Pollution, 141: 555-570.
  • Papadakis E., Papadakis N.Z., Kotopoulou A., Kintzikoglou K., Makris K.C., Papadopoulou-Mourkidou E. 2015. A pesticide monitoring survey in rivers and lakes of northern Greece and its human and ecotoxicological risk assessment. Ecotoxicology and Environmental Safety, 116: 1-9.
  • Satiroff J.A., Satiroff T.L., Mittelstet A.R., Snow D.D. 2021. Pesticide occurrence and persistence entering recreational lakes in watersheds of varying land use. Environmental Pollution, 273 (116399): 1-11.
  • Silva V., Mol H.G., Zomer P., Tienstra M., Ritsema C.J., Geissen V. 2019. Pesticide residues in European agricultural soils–A hidden realityunfolded. Science of the Total Environment, 653: 1532-1545.
  • Stolte J., Tesfai M., Oygarden L., Kvaerno S., Keizer J., Verheijen F., Panagos P., Ballabio C., Hessel R. 2016. Soil threats in Europe: Status, methods, drivers and effects on ecosystem services. JRC Science Hub, 1-206.
  • Garoiaz H., Berrabah M., Elidrissi A., Hammouti B., Ríos A. 2012. Analysis of cypermethrin residues and its main degradation products in soil and formulation samples by gas chromatography-electron impact- mass spectrometry in the selective ion monitoring mode. International Journal of Environmental Analytical Chemistry, 92 (12): 1378-1388.
  • Armenta S., Quintas G., Garrigues S., Guardia M. de la. 2005. A validated and fast pro-cedure for FTIR determination. Talanta, 67: 634-639.
  • Turkoz Altug D., Kaya Kinayturk N., Tunali B. 2020. The use of pumice to prevent penetration of cypermethrin into the soil. Fresenius Environmental Bulletin, 29 (12 A): 11266-11272.
  • Shukla Y., Yadav A., Arora A. 2002. Carcinogenic and cocarcinogenic potential of cypermethrin on mouse skin. Cancer Letters, 182: 33-41.
  • Yıldız A. 2014. Aktive edilmiş ceviz kabuğuna boyar madde adsorpsiyonu. Yüksek Lisans Tezi, Bozok Üniversitesi, Fen Bilimleri Enstitüsü, Yozgat.
  • Kanca A. 2019. Pamuk Atığı, Fındık Kabuğu ve Ceviz Kabuğu’nun Piroliz ve Oksidasyon Davranışlarının Kıyaslanması. Kocaeli Üniversitesi Fen Bilimleri Dergisi, 2 (2): 43-54.
  • Tang R., Dai C., Li C., Liu G.W.S., Wang C. 2017. Removal of Methylene Blue from Aqueous Solution Using Agricultural Residue Walnut Shell: Equilibrium, Kinetic, and Thermodynamic Studies. Hindawi Journal of Chemistry, 2017 (8404965): 1-10.
  • Li Z., Hanafy H., Zhang L., Sellaoui L., Netto M.S., Oliveira M.L., Seliem M.K., Dotto G.L., Bonilla-Petriciolet A., Li Q. 2020. Adsorption of congo red and methylene blue dyes on an ashitaba waste and a walnut shell-based activated carbon from aqueous solutions: Experiments, characterization and physical interpretations. Chemical Engineering Journal, 388 (15-124263): 1-10.
  • Orue A., Eceiza A., Arbelaiz A. 2020. The use of alkali treated walnut shells as filler in plasticized poly (lactic acid) matrix composites. Industrial Crops and Products, 145 (111993): 1-9.
  • Hemmati F., Jafari S.M., Kashaninejad M., Motlagh M. 2018. Synthesis and characterization of cellulose nanocrystals derived from walnut shell agricultural residues. International Journal of Biological Macromolecules, 120 (6): 1216-1224.
  • Demirbas E., Dizge N., Sulak M., Kobya M. 2009. Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon. Chemical Engineering Journal, 148 (2-3): 480-487.
  • Zhao B., Xu X., Zeng F., Li H., Chen X. 2018. The hierarchical porous structure bio-char assessments produced by co-pyrolysis of municipal sewage sludge and hazelnut shell and Cu(II) adsorption kinetics. Environmental Science and Pollution Research, 25: 19423-19435.
  • Demirbaş Ö., Karadağ A., Alkan M., Doğan M. 2008. Removal of copper ions from aqueous solutions by hazelnut shell. Journal of Hazardous Materials, 153 (1-2): 677-684.
  • Boumchita S., Lahrichi A., Benjelloun Y., Lairini S., Nenov V., Zerrouq F. 2017. Application of Peanut shell as a low-cost adsorbent for the removal of anionic dye from aqueous solutions. Journal of Materials and Environmental Science, 8 (7): 2353-2364.
  • Xu T., Liu X. 2008. Peanut Shell Activated Carbon: Characterization, Surface Modification and Adsorption of Pb2+ from Aqueous Solution. Chinese Journal of Chemical Engineering, 16 (3 June): 401-406.
  • Georgin J., Dotto G.L., Mazutti M.A., Foletto E.L. 2016. Preparation of activated carbon from peanut shell by conventional pyrolysis and microwave irradiation-pyrolysis to remove organic dyes from aqueous solutions. Journal of Environmental Chemical Engineering, 4 (1): 266-275.
  • Taşar Ş., Kaya F., Özer A. 2014. Biosorption of lead (II) ions from aqueous solution by peanut shells: equilibrium, thermodynamic and kinetic studies. Journal of Environmental Chemical Engineering, 2 (2): 1018-1026.
  • Segal-Rosenheimer M., Dubowski Y. 2007. Heterogeneous ozonolysis of cypermethrin us-ing real-time monitoring FTIR techniques. The Journal of Physical Chemistry C, 111: 11682-11691.
  • Altürk S., Tamer O., Avcı D., Atalay Y. 2015. Synthesis, spectroscopic characterization, second and third-order nonlinear optical properties, and DFT calculations of a novel Mn(II) complex. Journal of Organometallic Chemistry, 797: 110-119.
  • Mistry B. 2009. A Handbook of Spdectroscopic Data Chemistry. Oxford Book Company, 1-242.
  • Kaya N., Kartal Z., Bahçeli S. 2012. FT-IR Spectroscopic Investigation of Some M(Benzyl Chloride)2Ni(CN)4 Complex (M = Co, Ni and Cd). Dumlupınar Üniversitesi, Fen Bilimleri Enstitüsü Dergisi, 27 (Nisan): 23-34.
Year 2021, Volume: 10 Issue: 2, 362 - 369, 07.06.2021
https://doi.org/10.17798/bitlisfen.869932

Abstract

Project Number

-

References

  • Altıkat A., Turan T., Ekmekyapar Torun F. 2009. Türkiye’de Pestisit Kullanımı ve Çevreye Olan Etkileri. Atatürk Üniversitesi Ziraat Faültesi Dergisi, 40 (2): 87-92.
  • Hernández A.F., Parrónb T., Tsatsakis A.M., Requena M., Alarcón R., López-Guarnido O. 2013. Toxic effects of pesticide mixtures at a molecular level: Their relevance to human health. Toxicology, 307: 136-145.
  • Alavanja M.C., Hoppin J.A., Kamel F. 2004. Health Effects of Chronic Pesticide Exposure: Cancer and Neurotoxicity. Annual Review of Public Health, 25: 155-197.
  • Huang J., Qiao F., Zhang L., Rozelle S. 2000. Farm Pesticide, Rice Production and Human Health. CCAP's Project Report, 1-54.
  • Konstantinou I.K., Hela D.G., Albanis T.A. 2006. The status of pesticide pollution in surface waters (rivers and lakes) of Greece. Part I. Review on occurrence and levels. Environmental Pollution, 141: 555-570.
  • Papadakis E., Papadakis N.Z., Kotopoulou A., Kintzikoglou K., Makris K.C., Papadopoulou-Mourkidou E. 2015. A pesticide monitoring survey in rivers and lakes of northern Greece and its human and ecotoxicological risk assessment. Ecotoxicology and Environmental Safety, 116: 1-9.
  • Satiroff J.A., Satiroff T.L., Mittelstet A.R., Snow D.D. 2021. Pesticide occurrence and persistence entering recreational lakes in watersheds of varying land use. Environmental Pollution, 273 (116399): 1-11.
  • Silva V., Mol H.G., Zomer P., Tienstra M., Ritsema C.J., Geissen V. 2019. Pesticide residues in European agricultural soils–A hidden realityunfolded. Science of the Total Environment, 653: 1532-1545.
  • Stolte J., Tesfai M., Oygarden L., Kvaerno S., Keizer J., Verheijen F., Panagos P., Ballabio C., Hessel R. 2016. Soil threats in Europe: Status, methods, drivers and effects on ecosystem services. JRC Science Hub, 1-206.
  • Garoiaz H., Berrabah M., Elidrissi A., Hammouti B., Ríos A. 2012. Analysis of cypermethrin residues and its main degradation products in soil and formulation samples by gas chromatography-electron impact- mass spectrometry in the selective ion monitoring mode. International Journal of Environmental Analytical Chemistry, 92 (12): 1378-1388.
  • Armenta S., Quintas G., Garrigues S., Guardia M. de la. 2005. A validated and fast pro-cedure for FTIR determination. Talanta, 67: 634-639.
  • Turkoz Altug D., Kaya Kinayturk N., Tunali B. 2020. The use of pumice to prevent penetration of cypermethrin into the soil. Fresenius Environmental Bulletin, 29 (12 A): 11266-11272.
  • Shukla Y., Yadav A., Arora A. 2002. Carcinogenic and cocarcinogenic potential of cypermethrin on mouse skin. Cancer Letters, 182: 33-41.
  • Yıldız A. 2014. Aktive edilmiş ceviz kabuğuna boyar madde adsorpsiyonu. Yüksek Lisans Tezi, Bozok Üniversitesi, Fen Bilimleri Enstitüsü, Yozgat.
  • Kanca A. 2019. Pamuk Atığı, Fındık Kabuğu ve Ceviz Kabuğu’nun Piroliz ve Oksidasyon Davranışlarının Kıyaslanması. Kocaeli Üniversitesi Fen Bilimleri Dergisi, 2 (2): 43-54.
  • Tang R., Dai C., Li C., Liu G.W.S., Wang C. 2017. Removal of Methylene Blue from Aqueous Solution Using Agricultural Residue Walnut Shell: Equilibrium, Kinetic, and Thermodynamic Studies. Hindawi Journal of Chemistry, 2017 (8404965): 1-10.
  • Li Z., Hanafy H., Zhang L., Sellaoui L., Netto M.S., Oliveira M.L., Seliem M.K., Dotto G.L., Bonilla-Petriciolet A., Li Q. 2020. Adsorption of congo red and methylene blue dyes on an ashitaba waste and a walnut shell-based activated carbon from aqueous solutions: Experiments, characterization and physical interpretations. Chemical Engineering Journal, 388 (15-124263): 1-10.
  • Orue A., Eceiza A., Arbelaiz A. 2020. The use of alkali treated walnut shells as filler in plasticized poly (lactic acid) matrix composites. Industrial Crops and Products, 145 (111993): 1-9.
  • Hemmati F., Jafari S.M., Kashaninejad M., Motlagh M. 2018. Synthesis and characterization of cellulose nanocrystals derived from walnut shell agricultural residues. International Journal of Biological Macromolecules, 120 (6): 1216-1224.
  • Demirbas E., Dizge N., Sulak M., Kobya M. 2009. Adsorption kinetics and equilibrium of copper from aqueous solutions using hazelnut shell activated carbon. Chemical Engineering Journal, 148 (2-3): 480-487.
  • Zhao B., Xu X., Zeng F., Li H., Chen X. 2018. The hierarchical porous structure bio-char assessments produced by co-pyrolysis of municipal sewage sludge and hazelnut shell and Cu(II) adsorption kinetics. Environmental Science and Pollution Research, 25: 19423-19435.
  • Demirbaş Ö., Karadağ A., Alkan M., Doğan M. 2008. Removal of copper ions from aqueous solutions by hazelnut shell. Journal of Hazardous Materials, 153 (1-2): 677-684.
  • Boumchita S., Lahrichi A., Benjelloun Y., Lairini S., Nenov V., Zerrouq F. 2017. Application of Peanut shell as a low-cost adsorbent for the removal of anionic dye from aqueous solutions. Journal of Materials and Environmental Science, 8 (7): 2353-2364.
  • Xu T., Liu X. 2008. Peanut Shell Activated Carbon: Characterization, Surface Modification and Adsorption of Pb2+ from Aqueous Solution. Chinese Journal of Chemical Engineering, 16 (3 June): 401-406.
  • Georgin J., Dotto G.L., Mazutti M.A., Foletto E.L. 2016. Preparation of activated carbon from peanut shell by conventional pyrolysis and microwave irradiation-pyrolysis to remove organic dyes from aqueous solutions. Journal of Environmental Chemical Engineering, 4 (1): 266-275.
  • Taşar Ş., Kaya F., Özer A. 2014. Biosorption of lead (II) ions from aqueous solution by peanut shells: equilibrium, thermodynamic and kinetic studies. Journal of Environmental Chemical Engineering, 2 (2): 1018-1026.
  • Segal-Rosenheimer M., Dubowski Y. 2007. Heterogeneous ozonolysis of cypermethrin us-ing real-time monitoring FTIR techniques. The Journal of Physical Chemistry C, 111: 11682-11691.
  • Altürk S., Tamer O., Avcı D., Atalay Y. 2015. Synthesis, spectroscopic characterization, second and third-order nonlinear optical properties, and DFT calculations of a novel Mn(II) complex. Journal of Organometallic Chemistry, 797: 110-119.
  • Mistry B. 2009. A Handbook of Spdectroscopic Data Chemistry. Oxford Book Company, 1-242.
  • Kaya N., Kartal Z., Bahçeli S. 2012. FT-IR Spectroscopic Investigation of Some M(Benzyl Chloride)2Ni(CN)4 Complex (M = Co, Ni and Cd). Dumlupınar Üniversitesi, Fen Bilimleri Enstitüsü Dergisi, 27 (Nisan): 23-34.
There are 30 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Araştırma Makalesi
Authors

Deniz Türköz Altuğ 0000-0002-1861-6263

Project Number -
Publication Date June 7, 2021
Submission Date January 28, 2021
Acceptance Date April 12, 2021
Published in Issue Year 2021 Volume: 10 Issue: 2

Cite

IEEE D. Türköz Altuğ, “Ceviz, Fındık ve Yerfıstığı Kabuklarını Kullanarak Sipermetrinin Çevreden Uzaklaştırılması”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, vol. 10, no. 2, pp. 362–369, 2021, doi: 10.17798/bitlisfen.869932.

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Bitlis Eren University
Journal of Science Editor
Bitlis Eren University Graduate Institute
Bes Minare Mah. Ahmet Eren Bulvari, Merkez Kampus, 13000 BITLIS